Will Poulter also won two gongs at the Los Angeles event, winning the Breakthrough Performance accolade and his three-way We're The Millers smooch with Jennifer Aniston and Emma Roberts was named Best Kiss.

The Wolf Of Wall Street received two prizes, with Jonah Hill winning the Best Comedic Performance, while Leonardo DiCaprio scored the #WTF Moment Golden Popcorn.

[related]Other winners included Brad Pitt, Jared Leto and Channing Tatum, with Mark Wahlberg on hand to collect the MTV Generation Award.

However, the most memorable moment has to be when Zac Efron collected his Best Shirtless Performance award - only to have his top ripped off by presenter, Rita Ora!

Eminem and Rihanna performed The Monster for the first time, while Ellie Goulding, Zedd and Twenty One Pilots also took to the stage!

You can check out the 2014 MTV Movie Awards on Monday (April 14) at 9pm only on MTV!

Full 2014 MTV Movie Award Winners:

MOVIE OF THE YEAR

The Hunger Games: Catching Fire

BEST FEMALE PERFORMANCE

Jennifer Lawrence – The Hunger Games: Catching Fire

BEST MALE PERFORMANCE

Josh Hutcherson – The Hunger Games: Catching Fire

BREAKTHROUGH PERFORMANCE

Will Poulter – We’re the Millers

BEST KISS

Emma Roberts, Jennifer Aniston and Will Poulter – We’re the Millers

BEST FIGHT

The Hobbit: The Desolation of Smaug – Orlando Bloom and Evangeline Lilly vs. Orcs

BEST COMEDIC PERFORMANCE

Jonah Hill – The Wolf of Wall Street

BEST SCARED-AS-S**T PERFORMANCE

Brad Pitt – World War Z

BEST ON-SCREEN DUO

Vin Diesel and Paul Walker – Fast & Furious 6

#WTF MOMENT
Leonardo DiCaprio – The Wolf of Wall Street (Leonardo DiCaprio's iconic portrayal of excessive Wall Street player Jordan Belfort takes a turn for the insane when he takes his Lamborghini for a spin.)

BEST SHIRTLESS PERFORMANCE
Zac Efron – That Awkward Moment

BEST VILLAIN

Mila Kunis – Oz The Great and Powerful

BEST ON-SCREEN TRANSFORMATION

Jared Leto – Dallas Buyers Club

FAVOURITE CHARACTER

Shailene Woodley - Divergent

BEST MUSICAL MOMENT

Backstreet Boys, Jay Baruchel, Seth Rogen and Craig Robinson – This is the End (Spoiler alert! Backstreet Boys reunite in heaven to perform Everybody with signature boy band moves and flair for this unforgettable apocalyptic ending.)

BEST CAMEO PERFORMANCE

Rihanna – This is the End

BEST HERO

Henry Cavill as Clark Kent – Man of Steel

MTV TRAILBLAZER

Channing Tatum

MTV GENERATION AWARD

Mark Wahlberg