J-Law and gorgeous George will be joined by Anne Hathaway, Ben Affleck, Bradley Cooper, Christoph Waltz, Daniel Day-Lewis, Hugh Jackman, Jessica Chastain and Quentin Tarantino at the EE British Academy Film Awards.
And Sir Ian McKellen, Kevin Spacey, Samuel L Jackson, Danny Boyle and Sarah Jessica Parker will be among those attending and/or presenting awards.
Stephen Fry will be on hosting duties at Britain's biggest movie gong show - which will be broadcast on BBC One at 9pm.
We told you earlier today how J-Law has been joking about her Oscars outfit.
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