When posing for photos at the event, the former Pussycat Dolls star's William Vintage Ossie Clark frock turned sheer as a result of the camera flashes - leaving Scherzy exposing a little more than she would have liked.
Luckily for Nicole, her modesty was protected by some strategically placed nipple covers, as she smiled through her fashion faux pas.
Scherzinger's X Factor colleague Tulisa was also hit by a wardrobe malfunction at the event, as she flashed her huge Spanx when a gust of wind caught her Grecian-style gown.
Despite showing off her Bridget Jones-esque knickers, theN-Dubz stunner also unveiled off her killer curves in the low-cut, figure-hugging dress.
While Nicole and Tulisa may have stole the show with their head-turning frocks, The X Factor failed to win the Best Talent Show gong at the ceremony, losing out to Strictly Come Dancing.